Product ID:843 8145, DABMC
MSDS Date:08/27/1997
FSC:NIIN:Submitter:D DG
Status Code:A
MSDS Number: CKQRC

Emergency Phone: 716 722-5151

Info Phone: 716-722-5151/(800) 242-2424

Cage: 19139

Telephone: 716-722-5151/(800) 242-2424

Cage: 19139

2,6-BIS((4-AZYL)METHYLENE)-4-METHYLCYCLOHEXANONE (MSDS HAS

LD50 LC50 Mixture:ORAL LD-50 (RAT): > 3200 MG/KG
Routes of Entry: Inhalation:NO Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EFEECTS OF EXPOSURE: INHALATION:
EXPECTED TO BE A LOW HAZARD FOR RECOMMENDED HANDLING. EYES: CAUSES
IRRITATION. SKIN: CAUSES IRRITATION. MAY CAUSE ALLERGIC SKIN
REACTION. INGESTION: EXPECTED TO BE A L OW INGESTION HAZARD.
Explanation of Carcinogenicity:CARCINOGENICITY CLASSIFICATION
(COMPONENTS PRESENT AT 0.1% OR MORE): - INTERNATIONAL AGENCY FOR
RESEARCH ON CANCER (IARC): NONE - AMERICAN CONFERENCE OF
GOVERNMENTAL INDUSTRIAL HYGIENISTS (ACGIH): NON E - NATIONAL
TOXICOLOGY PROGRAM (NTP): NONE - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION (OSHA): NONE
Effects of Overexposure:EFEECTS OF EXPOSURE: INHALATION: EXPECTED TO BE
A LOW HAZARD FOR RECOMMENDED HANDLING. EYES: CAUSES IRRITATION.
SKIN: CAUSES IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION.
INGESTION: EXPECTED TO BE A L OW INGESTION HAZARD.
Medical Cond Aggravated by Exposure:NOT PROVIDED

First Aid:INHALATION: IF SYMPTOMATIC, MOVE TO FRESH AIR. GET MEDICAL
ATTENTION IF SYMPTOMS PERSIST. EYES: IMMEDIATELY FLUSH WITH
PLENTY OF WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION.
SKIN: IMMEDIATE LY REMOVE CONTAMINATED CLOTHING AND SHOES AND WASH
WITH SOAP AND PLENTY OF WATER. GET MEDICAL ATTENTION. WASH
CONTAMINATED CLOTHING BEFORE REUSE. DESTROY OR THOROUGHLY CLEAN
CONTAMINATED SHOES. INGEST ION: DRINK 1-2 GLASSES OF WATER. SEEK
MEDICAL ATTENTION. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS
PERSON.

Flash Point:NONE
Extinguishing Media:WATER SPRAY, CARBON DIOXIDE (CO2), DRY CHEMICAL.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
PROTECTIVE CLOTHING. FIRE OR EXCESSIVE HEAT MAY PRODUCE HAZARDOUS
DECOMPOSITION PRODUCTS. USE WATER SPRAY TO KEEP FIRE-EXPOSED
CONTAINERS COOL. FIGHT FIRE F ROM A PROTECTED LOCATION.
Unusual Fire/Explosion Hazard:POWDERED MATERIAL MAY FORM EXPLOSIVE
DUST-AIR MIXTURES. ELEVATED TEMPERATURES CAN CAUSE VIOLENT
DECOMPOSITION. RISK OF EXPLOSION IF HEATED UNDER CONFINEMENT.

Spill Release Procedures:COLLECT UP AND PUT IN A SUITABLE CONTAINER.
AVOID GENERATION OF DUST. CLEAN SURFACE THOROUGHLY TO REMOVE
RESIDUAL CONTAMINATION.
Neutralizing Agent:NOT PROVIDED

Handling and Storage Precautions:KEEP CONTAINER CLOSED. STORE IN A COOL
PLACE. PROTECT FROM LIGHT.
Other Precautions:AVOID CONTACT WITH EYES, SKIN, AND CLOTHING. USE WITH
ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. THE ROUTINE
USE OF A NONALKALINE (ACID) TYPE OF HAND CLEANER AND REGULAR
CLEANING OF WORKING SURFACES, GLOVES, ETC. WILL HELP MINIMIZE THE
POSSIBILITY OF A SKIN REACTION.

Respiratory Protection:NONE SHOULD BE NEEDED.
Ventilation:GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES PER
HOUR) SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO
CONDITIONS.
Protective Gloves:WEAR IMPERVIOUS GLOVES.
Eye Protection:WEAR SAFETY GLASSES WITH SIDE SHIELDS (OR GOGGLES).
Other Protective Equipment:EYE BATH, WASHING FACILITIES, SAFETY SHOWER.
Work Hygienic Practices:IT IS A GOOD INDUSTRIAL HYGIENE PRACTICE TO
MINIMIZE EYE CONTACT. IT IS A GOOD INDUSTRIAL HYGIENE PRACTICE TO
MINIMIZE SKIN CONTACT.
Supplemental Safety and Health

HCC:N1
Melt/Freeze Pt:M.P/F.P Text:NOT AVAILABLE
Vapor Pres:NOT AVAILABLE
Vapor Density:NOT AVAILA
Spec Gravity:NOT AVAILABLE
Solubility in Water:NOT AVAILABLE
Appearance and Odor:LIGHT YELLOW SOLID. ODOR: NOT AVAILABLE.
Percent Volatiles by Volume:NOT AVAILABL

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:STABLE; HOWEVER, MATERIAL CAN DECOMPOSE
VIOLENTLY ABOVE 105 C (221 F). AVOID TEMPERATURES ABOVE 55 C (131
F).
Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE,
OXIDES OF NITROGEN.
Conditions to Avoid Polymerization:WILL NOT OCCUR.

Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT
TO NATIONAL, STATE, OR LOCAL LAWS. INCINERATE. SINCE EMPTIED
CONTAINERS RETAIN PRODUCT RESIDUE, FOLLOW LABEL WARNINGS EVEN AFTER
CONTAINER IS EMPTIED.

Toxicological Information:DERMAL LD50: >1.0 GM/KG, SKIN IRRITATION:
SLIGHT, SKIN SENSITIZATION: SLIGHT, EYE IRRITATION 9UNWASHED EYES):
SLIGHT, EYE IRRITATION (WASHED EYES): SLIGHT. SUBACUTE TOXICITY
DATA: ORAL STUDY (10 DAYS, RAT): NO-OBSERVED-EFFECT LEVEL = 962
MG/KG/DAY

Ecological:FOLLOWING EFECTS EXPECTED: A LOW BIOCHEMICAL OXYGEN DEMAND &
LITTLE POTENTIAL TO CAUSE OXYGEN DEPLETION IN AQUEOUS SYSTEMS, A
LOW POTENTIAL TO EFFECT AQUATIC ORGANISMS, A LOW POTENTIAL TO
EFFECT SECON DARY WASTE TREATMENT MICROBIAL METABOLISM, A LOW
POTENTIAL TO PERSIST IN THE ENVIRONMENT, A LOW POTENTIAL TO
BIOACCUMULATE. AFTER DILUTION WITH A LARGE AMOUNT OF WATER,
FOLLOWED BY A SCONDARY WASTE TR EATMENT, THIS MATERIAL IS NOT
EXPECTED TO CAUSE ADVERSE ENVIRONMENTAL EFFECTS.

Transport Information:FOR TRANSPORTATION INFORMATION CONTACT KODAK
TRANSPORATION HAZAMT HOTLINE: 716-722-4000 BETWEEN 8AM - 5PM
(EASTERN STANDARD TIME) MONDAY THROUGH FRIDAY.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.